Removal of tartrazine in water using zero-valent iron nanoparticles
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Published:
Jul 15, 2019
Keywords:
nanopartículas de hierro cerovalentes, remoción, colorante, tartrazina iron zero valent nanoparticles, removal, dye, tartrazine
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Abstract
Due to the importance of an alternative to the decolorization of wastewater from the food industry, the removal of tartrazine dye is reported, using zero-valent iron nanoparticles. The nanoparticles were prepared by chemical reduction of ferric chloride with sodium borohydride in an inert medium. To evaluate the removal, concentrations of 25, 50, 100, 150 and 200 mg/L of nanoparticles were used, with contact times in water of 10, 20 and 30 minutes at pH of 3, 5, 7, 9 and 11. Scanning Electron Microscopy (SEM) and Energy Dispersive X-ray Spectroscopy (EDX) was used to characterize the nanoparticles obtained. As result, zero valent iron nanoparticles were obtained with an average size of 53.3 y 92.1 nm approximately. UV-Vis and Infrared Spectrophotometry with Fourier Transform (FT-IR) was used to verify the removal of the dye in water. The optimal parameters for the removal of tartrazine were given using 200 mg/L of nanoparticles, 30 minutes of agitation and pH 3 with an efficiency of 83.3 %. An adsorption of tartrazine of up to 301 mmol/100g (1659 mg/g) was achieved. It is concluded that zero valent iron nanoparticles are suitable for removal of tartrazine in water.
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References
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Alamillo, V. (2013). Remoción de colorantes orgánicos azul índigo y tartrazina, en solución acuosa, empleando nanopartículas de hierro soportadas en piedra volcánica de óxido de hierro (tezontle)(Tesis de pregrado). Toluca de Lerdo, México
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Borzelleca, J. F., & Hallagan, J. B. (1988). Chronic toxicity/carcinogenicity studies of FD & C Yellow No. 5 (tartrazine) in rats. Food and Chemical Toxicology, 26(3), 179– 187
Choulis, N. H. (2010). Miscellaneous drugs, materials, medical devices, and techniques. In Side Effects of Drugs Annual, 32, 891–902. Elsevier
Das, S., Dash, S. K., & Parida, K. M. (2018). Kinetics, Isotherm, and Thermodynamic Study for Ultrafast Adsorption of Azo Dye by an Efficient Sorbent: Ternary Mg/(Al + Fe) Layered Double Hydroxides. ACS Omega, 3(3), 2532–2545
Deepali, N. J. (2012). Study of ground water quality in and around SIDCUL industrial area, Haridwar, Uttarakhand, India. Journal of Applied Technology in Environmental Sanitation, 2(2), 129–134.
Fan, J., Guo, Y., Wang, J., & Fan, M. (2009). Rapid decolorization of azo dye methyl orange in aqueous solution by nanoscale zerovalent iron particles. Journal of Hazardous Materials, 166(2–3), 904–910
FDA, (2018) Listing of color additives subject to certification. 21 C.F.R. §74.705
Forgacs, E., Cserháti, T., & Oros, G. (2004). Removal of synthetic dyes from wastewaters: a review. Environment International, 30(7), 953–971.
Fu, Y., & Viraraghavan, T. (2001). Fungal decolorization of dye wastewaters: a review. Bioresource Technology, 79(3), 251–262.
Gonawala, K. H., & Mehta, M. J. (2014). Removal of Color from Different Dye Wastewater by Using Ferric Oxide as an Adsorbent. Int. Journal of Engineering Research and Applications, 4(5), 102–109.
Goscianska, J., & Pietrzak, R. (2015). Removal of tartrazine from aqueous solution by carbon nanotubes decorated with silver nanoparticles. Catalysis Today, 249, 259– 264
He, Y., Gao, J. F., Feng, F. Q., Liu, C., Peng, Y. Z., & Wang, S. Y. (2012). The comparative study on the rapid decolorization of azo, anthraquinone and triphenylmethane dyes by zero-valent iron. Chemical Engineering Journal, 179, 8–18.
Hu, D., Wan, X., Li, X., Liu, J., & Zhou, C. (2017). Synthesis of water-dispersible poly-Llysine-functionalized magnetic Fe3O4-(GO-MWCNTs) nanocomposite hybrid with a large surface area for high-efficiency removal of tartrazine and Pb(II). International Journal of Biological Macromolecules,105(2), 1611–1621.
König, J. (2015). Food colour additives of synthetic origin. In M. J. Scotter (Ed.), Colour Additives for Foods and Beverages, 36–60. Woodhead Publishing.
Leulescu, M., Rotaru, A., Plrie, I., Moan, A., Cioater, N., Popescu, M., … Rotaru, P. (2018). Tartrazine: physical, thermal and biophysical properties of the most widely employed synthetic yellow food-colouring azo dye. Journal of Thermal Analysis and Calorimetry, 134(1), 209–231
Lin, Y. H., Tseng, H. H., Wey, M. Y., & Lin, M. D. (2010). Characteristics of two types of stabilized nano zero-valent iron and transport in porous media. Science of the Total Environment, 408(10), 2260–2267
Maekawa, A., Matsuoka, C., Onodera, H., Tanigawa, H., Furuta, K., Kanno, J., … Ogiu, T. (1987). Lack of carcinogenicity of tartrazine (FD & C Yellow No. 5) in the F344 rat. Food and Chemical Toxicology, 25(12), 891–896.
Mao,Y., Xi, Z., Wang, W., Ma, C., &Yue, Q. (2015). Kinetics of solvent blue and reactive yellow removal using microwave radiation in combination with nanoscale zerovalent iron. Journal of Environmental Sciences, 30, 164–172.
Mateus, G. A. P., dos Santos, T. R. T., Sanches, I. S., Silva, M. F., de Andrade, M. B., Paludo, M. P., … Bergamasco, R. (2018). Evaluation of a magnetic coagulant based on Fe3O4 nanoparticles and Moringa oleifera extract on tartrazine removal: coagulation-adsorption and kinetics studies. Environmental Technology, 1, 1-16.
Merck KGaA. (2019). Tartrazine. Retrieved from https://www.sigmaaldrich.com/catalog/ product/sigma/t0388?lang=en®ion=EC
Moutinho, I., Bertges, L., & Assis, R. (2007). Prolonged use of the food dye tartrazine (FD&C yellow n° 5) and its effects on the gastric mucosa of Wistar rats. Brazilian Journal of Biology, 67(1), 141–145.
Nam, S., & Tratnyek, P. G. (2000). Reduction of azo dyes with zero-valent iron. Water Research, 34(6), 1837–1845.
Poul, M., Jarry, G., Elhkim, M. O., & Poul, J.-M. (2009). Lack of genotoxic effect of food dyes amaranth, sunset yellow and tartrazine and their metabolites in the gut micronucleus assay in mice. Food and Chemical Toxicology, 47(2), 443–448.
Raman, C. D., & Kanmani, S. (2016). Textile dye degradation using nano zero valent iron: A review. Journal of Environmental Management, 177, 341–355.
Sohrabi, M. R., Amiri, S., Masoumi, H. R. F., & Moghri, M. (2014). Optimization of Direct Yellow 12 dye removal by nanoscale zero-valent iron using response surface methodology. Journal of Industrial and Engineering Chemistry, 20(4), 2535–2542.
Spina, F., Anastasi, A. E., Prigione, V. P., Tigini, V., & Varese, G. (2012). Biological treatment of industrial wastewaters: a fungal approach.
Sun, Y. P., Li, X. Q., Cao, J., Zhang, W. X., & Wang, H. P. (2006). Characterization of zero-valent iron nanoparticles. Advances in Colloid and Interface Science, 120(1– 3), 47–56.
Tran, H. V, Tran, T. L., Le, T. D., Le, T. D., Nguyen, H. M. T., & Dang, L. T. (2018). Graphene oxide enhanced adsorption capacity of chitosan/magnetite nanocomposite for Cr(VI) removal from aqueous solution. Materials Research Express, 6(2), 025018.
Zhao, Z., Liu, J., Tai, C., Zhou, Q., Hu, J., & Jiang, G. (2008). Rapid decolorization of water soluble azo-dyes by nanosized zero-valent iron immobilized on the exchange resin. Science in China Series B: Chemistry, 51(2), 186–192.
Aksu, Z., Tatlı, A. ., & Tunç, Ö. (2008). A comparative adsorption/biosorption study of Acid Blue 161: Effect of temperature on equilibrium and kinetic parameters. Chemical Engineering Journal, 142(1), 23–39
Alamillo, V. (2013). Remoción de colorantes orgánicos azul índigo y tartrazina, en solución acuosa, empleando nanopartículas de hierro soportadas en piedra volcánica de óxido de hierro (tezontle)(Tesis de pregrado). Toluca de Lerdo, México
Bigg, T., & Judd, S. J. (2002). Reductive degradation of azo dyes in aqueous solution by zero-valent iron. IAHS PUBLICATION, 383–390
Borzelleca, J. F., & Hallagan, J. B. (1988). Chronic toxicity/carcinogenicity studies of FD & C Yellow No. 5 (tartrazine) in rats. Food and Chemical Toxicology, 26(3), 179– 187
Choulis, N. H. (2010). Miscellaneous drugs, materials, medical devices, and techniques. In Side Effects of Drugs Annual, 32, 891–902. Elsevier
Das, S., Dash, S. K., & Parida, K. M. (2018). Kinetics, Isotherm, and Thermodynamic Study for Ultrafast Adsorption of Azo Dye by an Efficient Sorbent: Ternary Mg/(Al + Fe) Layered Double Hydroxides. ACS Omega, 3(3), 2532–2545
Deepali, N. J. (2012). Study of ground water quality in and around SIDCUL industrial area, Haridwar, Uttarakhand, India. Journal of Applied Technology in Environmental Sanitation, 2(2), 129–134.
Fan, J., Guo, Y., Wang, J., & Fan, M. (2009). Rapid decolorization of azo dye methyl orange in aqueous solution by nanoscale zerovalent iron particles. Journal of Hazardous Materials, 166(2–3), 904–910
FDA, (2018) Listing of color additives subject to certification. 21 C.F.R. §74.705
Forgacs, E., Cserháti, T., & Oros, G. (2004). Removal of synthetic dyes from wastewaters: a review. Environment International, 30(7), 953–971.
Fu, Y., & Viraraghavan, T. (2001). Fungal decolorization of dye wastewaters: a review. Bioresource Technology, 79(3), 251–262.
Gonawala, K. H., & Mehta, M. J. (2014). Removal of Color from Different Dye Wastewater by Using Ferric Oxide as an Adsorbent. Int. Journal of Engineering Research and Applications, 4(5), 102–109.
Goscianska, J., & Pietrzak, R. (2015). Removal of tartrazine from aqueous solution by carbon nanotubes decorated with silver nanoparticles. Catalysis Today, 249, 259– 264
He, Y., Gao, J. F., Feng, F. Q., Liu, C., Peng, Y. Z., & Wang, S. Y. (2012). The comparative study on the rapid decolorization of azo, anthraquinone and triphenylmethane dyes by zero-valent iron. Chemical Engineering Journal, 179, 8–18.
Hu, D., Wan, X., Li, X., Liu, J., & Zhou, C. (2017). Synthesis of water-dispersible poly-Llysine-functionalized magnetic Fe3O4-(GO-MWCNTs) nanocomposite hybrid with a large surface area for high-efficiency removal of tartrazine and Pb(II). International Journal of Biological Macromolecules,105(2), 1611–1621.
König, J. (2015). Food colour additives of synthetic origin. In M. J. Scotter (Ed.), Colour Additives for Foods and Beverages, 36–60. Woodhead Publishing.
Leulescu, M., Rotaru, A., Plrie, I., Moan, A., Cioater, N., Popescu, M., … Rotaru, P. (2018). Tartrazine: physical, thermal and biophysical properties of the most widely employed synthetic yellow food-colouring azo dye. Journal of Thermal Analysis and Calorimetry, 134(1), 209–231
Lin, Y. H., Tseng, H. H., Wey, M. Y., & Lin, M. D. (2010). Characteristics of two types of stabilized nano zero-valent iron and transport in porous media. Science of the Total Environment, 408(10), 2260–2267
Maekawa, A., Matsuoka, C., Onodera, H., Tanigawa, H., Furuta, K., Kanno, J., … Ogiu, T. (1987). Lack of carcinogenicity of tartrazine (FD & C Yellow No. 5) in the F344 rat. Food and Chemical Toxicology, 25(12), 891–896.
Mao,Y., Xi, Z., Wang, W., Ma, C., &Yue, Q. (2015). Kinetics of solvent blue and reactive yellow removal using microwave radiation in combination with nanoscale zerovalent iron. Journal of Environmental Sciences, 30, 164–172.
Mateus, G. A. P., dos Santos, T. R. T., Sanches, I. S., Silva, M. F., de Andrade, M. B., Paludo, M. P., … Bergamasco, R. (2018). Evaluation of a magnetic coagulant based on Fe3O4 nanoparticles and Moringa oleifera extract on tartrazine removal: coagulation-adsorption and kinetics studies. Environmental Technology, 1, 1-16.
Merck KGaA. (2019). Tartrazine. Retrieved from https://www.sigmaaldrich.com/catalog/ product/sigma/t0388?lang=en®ion=EC
Moutinho, I., Bertges, L., & Assis, R. (2007). Prolonged use of the food dye tartrazine (FD&C yellow n° 5) and its effects on the gastric mucosa of Wistar rats. Brazilian Journal of Biology, 67(1), 141–145.
Nam, S., & Tratnyek, P. G. (2000). Reduction of azo dyes with zero-valent iron. Water Research, 34(6), 1837–1845.
Poul, M., Jarry, G., Elhkim, M. O., & Poul, J.-M. (2009). Lack of genotoxic effect of food dyes amaranth, sunset yellow and tartrazine and their metabolites in the gut micronucleus assay in mice. Food and Chemical Toxicology, 47(2), 443–448.
Raman, C. D., & Kanmani, S. (2016). Textile dye degradation using nano zero valent iron: A review. Journal of Environmental Management, 177, 341–355.
Sohrabi, M. R., Amiri, S., Masoumi, H. R. F., & Moghri, M. (2014). Optimization of Direct Yellow 12 dye removal by nanoscale zero-valent iron using response surface methodology. Journal of Industrial and Engineering Chemistry, 20(4), 2535–2542.
Spina, F., Anastasi, A. E., Prigione, V. P., Tigini, V., & Varese, G. (2012). Biological treatment of industrial wastewaters: a fungal approach.
Sun, Y. P., Li, X. Q., Cao, J., Zhang, W. X., & Wang, H. P. (2006). Characterization of zero-valent iron nanoparticles. Advances in Colloid and Interface Science, 120(1– 3), 47–56.
Tran, H. V, Tran, T. L., Le, T. D., Le, T. D., Nguyen, H. M. T., & Dang, L. T. (2018). Graphene oxide enhanced adsorption capacity of chitosan/magnetite nanocomposite for Cr(VI) removal from aqueous solution. Materials Research Express, 6(2), 025018.
Zhao, Z., Liu, J., Tai, C., Zhou, Q., Hu, J., & Jiang, G. (2008). Rapid decolorization of water soluble azo-dyes by nanosized zero-valent iron immobilized on the exchange resin. Science in China Series B: Chemistry, 51(2), 186–192.