REMOVAL OF ORGANIC AZOIC DYES CONGO RED AND METHYL VIOLET IN WATER SOLUTIONS USING ZEROVALENT IRON NANOPARTICLES COATED WITH Solanum mammosum L
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Abstract
The usage of azo dyes can induce a variety of allergy disorders and may even be carcinogenic. The effect of zerovalent iron nanoparticles coated with an aqueous plant extract of Solanum mammosum L. (8.9±2,8 nm) on Congo red and methyl violet dyes in water was investigated in this work. The approach included conditioning the removal process with zerovalent iron nanoparticles without coating as a blank (24.8±6.1 nm). The UV-Vis absorption spectra of the dyes were obtained, and the best removal parameters in terms of adsorbent quantity (0 to 200 mgL -1 ), pH (3, 5, 9, and 11), and contact time by agitation were identified (0 to 30 min). Moreover, the nanoparticles were examined using transmission electron microscopy, scanning electron microscopy, X-ray diffraction and infrared spectroscopy. Because of utilizing of FeNPs-S. mammosum L., the comparative percentage of Congo red dye removal increased from 94.31 to 98.84% and methyl violet removal from 96.28 to 99.90%. It is concluded that zerovalent iron nanoparticles coated with a plant extract are a cost-effective and ecologically friendly option for organic azo dye decontamination operations in water.
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